Websition from nonpolar I4/mmm to polar A21am agrees with previous reports.11,12 In the middle T range (e.g. ∼ 300 −600 K), the mixture of multiple structures in-cluding I4/mmm, A21am, as well as the intermediate Amam, are evidenced, further confirming the compli-cated structural evolution from paraelectric to ferroelec-tric states. WebJul 1, 2024 · According to the high-temperature X-ray diffraction results, the exothermic effect in the range of 1123–1223 K is related to ferroelectric phase transition from polar (A2 1 am) to nonpolar phase (I4/mmm). The high-temperature X-ray diffraction detected no reconstructive phase transitions in calcium bismuth niobate or its solid solution in the ...
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